Wednesday, October 30, 2019
Maple Leaf Shoes Ltd Assignment Example | Topics and Well Written Essays - 500 words
Maple Leaf Shoes Ltd - Assignment Example Such discrimination is uncalled for and no matter individualââ¬â¢s status of HIV virus infection one has to be human; enough with each other and any form of segregation is unjust and controversial of to the human rights. In this case, Jon should be candid enough and openly state the fact as they are. HIV infection is not in any point a measure of alienating individuals from us or discriminating them from being part, participating or engaging in any thing anyone else is doing. Jon should advice the supervisor that the HIV-virus infected people should be treated with just, fairness and love. The transmission of the HIV virus infection is not in any way through working with the individual or just mere contact and therefore no isolation or evil perception towards such people in the society we live in. The development of the policy on AIDS would benchmark on the fact that we live a society where we are well endowed with knowledge and tools required to slow the spread of HIV infection and result to improvement of the health of people living with HIV. There is need to take bold steps in ensuring that the policy is effective since we face an era of rising infections, coupled with enormous challenges in serving individuals with HIV, and also a higher health care costs. Formulation of a well-coordinated national and institution level response to the HIV epidemic. The strategy is geared towards a concise plan that will identify a set of strategic actions and set of priorities linked to measurable outcomes. As an institution, the set strategies should be accompanied with particular steps that are supposed to be taken by various stakeholders within the government and other institutions in support of the high-level priorities as outlined in the policy. The success of all these is through a coordinated national response towards the epidemic. This calls for commitment from every level of the
Monday, October 28, 2019
Cyber war Vs Cyber terrorism Essay Example for Free
Cyber war Vs Cyber terrorism Essay In this time and era, we have witnessed the emergence of electronic resources as the most important development of the modern day communication system. Technologies such as cellular phones, home computers, the internet and websites have added another dimension to the way we live our lives today. This presentation seeks to address and analyse the negative and positive aspects in view of the introduction of computers and telecommunications techniques as follows: Firstly, it raises awareness with regard to the new age of crimes, termed as cyber crimes. The paper focuses, in particular, on the difference between the two common types of cyber crimes, cyber war and cyber terrorism. Secondly, the paper examines the limitations and impact of having graduates through e-learning. Thirdly and lastly, the paper discusses on whether computer practitioners should be required to have a practicing license as it is with other professionals such as doctors, lawyers and teachers. 1. (a) Difference Between Cyber War and Cyber Terrorism The end result of both cyber war and cyber terrorism is the same, to damage critical infrastructures and computer systems. The major difference beingà that cyber war is launched by governments whereas cyber terrorism is launched by individuals or a group of individuals. Cyber war, often done in conjunction with traditional military attacks, is an organised attack by one nation against another nationââ¬â¢s information and communication systems with an aim of gaining an advantage over the enemy by disrupting their ability to fight back. Cyber war attacks often targets an enemies systems such as command and control systems, intelligence collection and distribution, information processing and distribution, tactical communication, troop and weapons positioning and so on. For instance, when the United States of America invaded Iraq, they disrupted the countryââ¬â¢s communication and defence systems, crippling their ability to find and take down US aircrafts. On the other hand, cybe r terrorism is when individuals or terrorist groups use computers, computer networks and the internet against persons or property to intimidate or coerce government, civilians, society in order to reach political, religious or ideological agenda. The things that are targeted are power plant systems, telephone systems, transportation systems, water or oil pipelines, financial institutions and so on. ([online] Available at: community.mis.temple.edu/mis2901001â⬠¦[Accessed 5 April 2014]) Cyber terrorism takes many forms. One of the more popular is to threaten a large bank. The terrorist hacks into the bankââ¬â¢s system and then leave an encrypted message for senior directors demanding for a sum of money. If the bank does not cooperate, the terrorist threatens to use anything from logic bombs to electromagnetic pulses and high-emission guns to destroy the bankââ¬â¢s files. Most banks would rather pay the money than have the public know how vulnerable they are for fear of loss of business. ([online] Available at: csciwww.etsu.edu/../cases.htm [Accessed 6 April 2014]) One practical example is where banks in Zambia have lost an estimated US$4 million to cybercrime through Automated Teller Machines (ATMs) withdrawals. This was reported in the local Post newspaper dated 14 June 2013. This was after the state police discovered a scam in which three foreign criminals had recruited and trained Zambians in cyber-crime. ([online] Available at: www.postzambia.com/post-read article [Accessed 6 April 2014]) Cyber terrorism can also include terrorists getting secret data from defence files, network with other terrorists, or raise and manage funds for terrorism by hacking. (b) Limitations and Impact of Having Graduates à Through E-learning E-learning has become an increasingly popular learning approach in higher educational institutions due to the rapid growth of internet technologies. Many foreign renowned universities offer all types of programmes ranging from Bachelor, Master and PhD programmes, to Short Courses. Essentially, emerging evidence suggests that having graduates through e-learning has substantial beneficial impact on social and economic development of our societies today and includes the following. It has enhanced skills development to would be graduates and their countries to cope with the demands of the 21st century where rapid change and globalisation is taking place. For instance, graduates have acquired an improved ability to conduct independent research, think critically to solve problems through the use of e-technology to communicate and collaborate. It has lead to an increased student turnover because of its flexibility and cost effectiveness and hence has broadened educati onal opportunity for many, especially financially disadvantaged students and those with disabilities. This has resulted in an increased human resource base and enhanced economic progress from direct job creation in the technology industry as well as from developing a better educated work force, much needed in developing countries such as Zambia. Online access promises a new access route for millions of students. This new approach of learning facilitates different students at different continents to attend the same classes almost at the same time. It has brought about improved learning methods and teachers have a more positive attitude towards their work and are able to provide personalized learning. On the other hand, although e-learning has brought about many benefits for students and organizations alike, it also has its limitations. In order to perform the tasks required by system, an e-learning environment requires basic state of the art equipment and minimum level of computer skills. Thus, a student that does not have the minimum computer knowledge, or have access to these equipment is disadvantaged and will not succeed in an e-learning program. Certain subjects, such as sports and public speaking, require physical exertion and practice. Thus, they cannot be applied in an e-learning environment. Needless to say, it can be a useful companion to traditional education for teaching backgroun d and technical information. A successful e-learning program requires students that are well organised, self motivated and haveà good time management skills. In other words, an e-learning program is directly related to the amount of effort applied. Successful e-learning students are able to study independently and incorporate study time into their busy lives. Students that lack discipline and are not good at time management are disadvantaged and will not succeed. E-learning requires good reading and writing skills. Most activities and communications are written, and thus, the ability to efficiently interpret instructions is a critical skill to a successful e-learning program. Students that are not comfortable with the ability to express themselves through writing will not succeed in e-learning. 2. Are computer practitioners similar enough to other professionals that they should be required to have a License too? Licensing is not currently required for computer practitioners but is being considered by several professional computing organizations and is believed, in principle, as necessary as the certification and licensing of doctors, lawyers, teachers, hairdressers and other professionals. The question of licensing professional s in general is a very controversial and political question. Licensing generally means that to practice a certain profession requires a government licensee, usually administered through a professional organization. The general theory of licensing professional is that it is supposed to help the general public outside the professional to be assured that someone else is capable of doing certain jobs. For instance,à one of the top e-learning institutions, the University of Liverpool in conjunction with Laureate Online Education offer 41 distance learning courses from a wide area of disciplines. The notion that degrees through e-learning are perceived not to be as rewarding or valuable as full-time traditional degree has been proved not to be the case. In fact, in the late 1990s, the Quality Assurance Agency for Higher Education of the British Government measured academic excellence in more than 100 universities, including the Open University. Surprisingly, the Open University was ranked in the top ten of British Universities in terms of academic excellence. The only underlying difference between a traditional degree and e-learning degree is the manner in which information is conveyed. The traditional setup has been based on a face to face communication where students and lecturers are brought together at the same time and the same place in classes,à laboratories and recreation centers for the purpose of learning, whereas in e-learning systems use technology to separate the learner from the teacher, and the learner from the learning group while maintaining the integrity of the learning process. Follow up statistics placing the Open University in the top 10 with Oxford and Cambridge have been repeated for several years and cannot be statistically be explained as a mere coincidence. ([online] Available at: http.//www.webbasedtraining.com/ [Accessed 3 March 2014]) The main focus of this presentation is to gain insights into critical issues confronting two major stakeholders in the new era of WBT, the student and faculty. The question at hand requires objective views on the advantages and disadvantages of WBT from a studentââ¬â¢s point of view as well as advantages of WBT from the collegeââ¬â¢s point of view. It further requires identifying ways that studying from a website is better than studying from written text as well as discuss in details the social and economical benefits and limitations of E-technology in Zambia. Systems Development Life Cycle The second part of this presentation discusses a linier Systems Development Life Cycle (SDLC) which is a technique used to assist developers effectively develop information systems. ââ¬ËGaining competitive advantage and improving information delivery will urge an organization to restructure its activities. The information system has to be developed to suite the business scenario and objectives. It needs to be carefully planned and activities well thought of.ââ¬â¢ (Ndhlovu, 2009). Thus, in an effort to answer the question at hand a description of the stages involved in a SDLC using annotated diagram shall be discussed. In addition, the discussion shall also include a description of techniques which can be used to investigate the existing system of an organization identifying the advantages and disadvantages of each and also give an alternative to SDLC for developing systems. Having said that, details of the mentioned topics in question is as follows. a) Web-Based Training Advantages and Disadvantages of WBT: Studentââ¬â¢s Point of View Advantages Utilisation of the World Wide Web is a current and extensive source ofà information and relatively easy to use. Some of the advantages from a studentââ¬â¢s point of view include the following. There is unlimited source of information on the internet as compared to textbooks and class lectures as it provides a variety and quality of learning materials. Encountering a new experience of sourcing information on the web increases a motivation to learn among students. For example, the web allows browsing from one link to another on a particular subject or topic Access to meaningful resources foster critical thinking skills and allows the student to see new ways of interpreting and evaluating information. For instance, gathering view points and knowledge from various internet sites cause students to debate previously held values and ideas which they may have had misconceptions. Gain of competence with technology by learning to navigate and use the web successfully, apply computer skill s, use of conferencing tools such as e-mail and listservs. Integration of technology with content-related work provided a more meaningful interaction with the subject matter. For example, students reflected on the lack of relevance in acquiring computer skills in isolation noting that when combined with content, those applications become a tool to improve learning in their field of study. Technological aspects of course assignments encourage cooperative dialogue rather than isolation. For example, e-mail and listservs are used regularly providing a valuable resource for support and collaboration among classmates for help in completing assignments, support with technological frustration and to share acquired skills or content resources. In addition, e-mail communication with instructors gives a student individual attention that is not apparent in a traditional coursework setup. E-mail utilization has many assets that face-to-face classroom contact lacks. For example, student need not wait for class time in order to get or clarify a piece of information. The student who would normally shy away and not ask a question in class or participate in a class discus sion are more comfortable using e-mail as a medium of communication and thus is not left out on the much needed information. For the student, online course allows them to integrate work, family and school more efficiently as it eliminates travel time to and from class for commuters. Disadvantages The positive aspects of WBT are countered with some frustrations that areà experienced by some students. These include the following. Student lack of computer skills, internet server being down, difficulty in accessing computer, use of obsolete computers and lack of technical and instructional support are some of the frustrations that a student may encounter. Required assignments are time consuming as mastering computer application tools and learning to navigate the web efficiently take up most of the time. Advantages of WBT: Collegeââ¬â¢s Point of View Higher education is evolving, consumer needs are shifting, and competition for students is increasing. Consequently, institutions must be driven to some extent by the needs and demands of the consumer. To satisfy the unique needs of growing numbers of nontraditional students and to make graduate degrees more attractive and feasible, the availability of online courses and distance learning opportunities is essential. Most of the faculties consider technology applications in university courses as the wave of the future citing their main reason for wanting its continuity as mainly being the benefits they believe their students receive. Moreover, in this time and era, a faculty member who does not use technology is often considered out of date and out of touch with skills that are needed for the coming millennium. Faculty respondents consistently identified convenience and improved learning as advantages for students enrolled in Web-based instruction. Other advantages identified by facul ty are as follows. Students gain knowledge on how to use numerous technology-based applications such as e-mail, PowerPoint, listservs, graphics programs, and HTML, many of which are considered essential skills for todayââ¬â¢s workforce. Students also gain comfort with the medium, anxiety levels are reduced, and they are more willing to explore the potential of technology applications. Students tend to become independent learners, are more motivated to explore related topics on their own, and develop critical thinking skills. The quality of completed assignments is often better than in the traditional classroom because students have more time for reflection and better access to resources. More information can be included in a course with the potential for students to expand on the information received by providing links to related sites. Many students will click on a link more readily than obtaining a print resource identified in a bibliography. Students learning how to access the extensiveà resources available on the WWW, online databases, and other technology-based resources. Student convenience. For example, online classes provide students with 24-hour access, eliminate the need to travel or find parking, and eliminate scheduling conflicts with jobs or family. These advantages may particularly benefit graduate students and nontraditional students. Connecting s tudents with technology allows the student to become part of a global community. Information and ideas can be exchanged with other students and experts throughout the world using e-mail and listserv discussions. Collaboration and communication among students are fostered, as well as communication between instructor and student. Online Studying Vs. Written Text Studying Among the several ways that studying from a website is better than studying from written text three distinct ways include the following. Text books become outdated almost immediately after publication and cannot be updated until the next publication which may take several years down the line. Information on the website can be updated daily and printing errors are corrected immediately. Written text is limited to the information on the page whereas educational websites can link to an infinite number of other educational sites to give supplemental detail in as much as possible on a particular subject or topic. Textbooks are limited to the points of view of their authors whereas the website allows multiple view points, which is essential for critical thinking especially if the author is too vague about a particular topic. ([online] Available at: English.varsavskyfoundation.org/education [Accessed 7 March 2014]) b) Social and Economical Benefits and Limitations of E-technology in Zambia Zambia is one of a number of countries in the Southern African region that have sought to include e-technology in its national development plans. E-technology is believed to contribute to improving development outcomes in two main ways: E-technology-based knowledge and products contribute directly to wealth creation. The use of e-technology contributes indirectly to national development through its impact in social and economic sectors such as agriculture, health and education, and by empowering individuals to take advantage of new opportunities. For example,à AfriConnect, in partnership with the Zambian Ministry of Education, have been piloting a project aimed at bringing web-based e-learning to schools in different parts of the country. The objective is to move from the traditional chalk-and-talk pedagogy to enquiry-based learning, while at the same time bringing the option of lifelong learning to people who have already left school. Individuals also benefit from the availability and use of e-technology in a number of ways. For example, by substituting phone calls for travel, which saves time and money, and by using e-technology to obtain information on prices, for their own produce and for purchases. In these various ways, e-technology can have a significant impact on a countryââ¬â¢s ability to achieve the Millennium Development Goals (MDGs). There are, however, also constraints on the potential impact of e-technology in many developing countries. These constraints include inadequate technical infrastructure, limited human skills to use available networks and services, the relatively high cost of communications equipment, and poor policy and regulatory environments. These factors reduce the scope for countries and communities to realise the potential of e-technology for development. Question 2 Solution (a) Model of the Systems Development Life Cycle highlighting the maintenance PhaseThe systems development life cycle (SDLC) is a conceptual model used in project management that describes the stages involved in an information system development project, from an initial feasibility study through maintenance of the completed application. In general, an SDLC methodology follows the following steps: 1. Planning Stage The existing system is evaluated. Deficiencies are identified. This can be done by interviewing users of the system and consulting with support personnel. 2. Analysis Stage The new system requirements are defined. In particular, the deficiencies in the existing system must be addressed with specific proposals for improvement. 3. Design Stage The proposed system is designed. Plans are laid out concerning the physicalà construction, hardware, operating systems, programming, communications, and security issues. The new system is developed. The new components and programs must be obtained and installed. Users of the system must be trained in its use, and all aspects of performance must be tested. If necessary, adjustments must be made at this stage. 4. Implementation Stage The system is put into use. This can be done in various ways. The new system can be phased in, according to application or location, and the old system gradually replaced. In some cases, it may be more cost-effective to shut down the old system and implement the new system all at once. 5. Maintenance Stage Once the new system is up and running for a while, it should be exhaustively evaluated. Maintenance must be kept up rigorously at all times. Users of the system should be kept up-to-date concerning the latest modifications and procedures. (b) The systems development life cycle (SDLC), also referred to as the application development life-cycle, is a term used in systems engineering, information systems and software engineering to describe a process for planning, creating, testing, and deploying an information system.[1] The systems development life-cycle concept applies to a range of hardware and software configurations, as a system can be composed of hardware only, software only, or a combination of both.[2] The waterfall model is a sequential design process, often used in software development processes, in which progress is seen as flowing steadily downwards (like a waterfall) through the phases of Conception, Initiation, Analysis, Design, Construction, Testing, Production/Implementation, and Maintenance. What is systems development life cycle (SDLC)? (SDLC is also an abbreviation for Synchronous Data Link Control.) The systems development life cycle (SDLC) is a conceptual model used in projectà management that describes the stages involved in an information system development project, from an initial feasibility study through maintenance of the completed application. Various SDLC methodologies have been developed to guide the processes involved, including the waterfall model (which was the original SDLC method); rapid application development (RAD); joint application development (JAD); the fountain model; the spiral model; build and fix; and synchronize-and-stabilize. Frequently, several models are combined into some sort of hybrid methodology. Documentation is crucial regardless of the type of model chosen or devised for any application, and is usually done in parallel with the development process. Some methods work better for specific types of projects, but in the final analysis, the most important factor for the success of a project may be how closely the particular plan was followed. In general, an SDLC methodology follows the following steps: 6. The existing system is evaluated. Deficiencies are identified. This can be done by interviewing users of the system and consulting with support personnel. 7. The new system requirements are defined. In particular, the deficiencies in the existing system must be addressed with specific proposals for improvement. 8. The proposed system is designed. Plans are laid out concerning the physical construction, hardware, operating systems, programming, communications, and security issues. 9. The new system is developed. The new components and programs must be obtained and installed. Users of the system must be trained in its use, and all aspects of performance must be tested. If necessary, adjustments must be made at this stage. 10. The system is put into use. This can be done in various ways. The new system can phased in, according to application or location, and the old system gradually replaced. In some cases, it may be more c ost-effective to shut down the old system and implement the new system all at once. 11. Once the new system is up and running for a while, it should be exhaustively evaluated. Maintenance must be kept up rigorously at all times. Users of the system should be kept up-to-date concerning the latest modifications and procedures.
Saturday, October 26, 2019
Free Hamlet Essays: Freud and Hamlet :: GCSE Coursework Shakespeare Hamlet
Hamlet Essay:à Freud and Hamlet à Freud believed that Hamlet did not kill Claudius the first time he saw him because Hamlet saw himself as the enemy. This sounds like a solid reason to me.à Who am I to say that it is not?à However,à I also findà Samuel Taylor Coleridge'sà reasoning very interesting.à He believed that Hamlet did not kill Claudius the first time because he was praying.à This sounds almost too easy, although very legitimate.à Now, I am not one to say which interpretation is right, or even ponder if either is right; however, they both come credible critics. So, who is right and who is wrong--that is the question?à No?à Maybe both are right to an extent. We do not actually know what Shakespeare was feeling when writing Hamlet.à à à This brings me to the point Chris Early made previously.à I, like Chris, do not believe that works should only be investigated on the surface, but it is difficult to uncover every meaning of every aspect of every work.à Is there always something bigger and more meaningful than the original words?à Sometimes I would say yes, and sometimes no.à So, this leads me to my next question: how does one know if the words mean something bigger or not?à I believe that there is no actual way to know if something has hidden meaning or not; therefore, almost everything is scrutinized as if it does.à I am not trying to make silly excuses;à I am being completely serious.à No one, even the great critics, know what is symbolic and what is not; therefore everything is considered symbolic in the beginning, causing some sort of symbolism to be uncovered.à à Whether this symbolism is correct, no one will actually know.à As Chris touched on, who knows what Shakespeare was thinking when writing Hamlet?à We can only make educated guesses at what Hamlet was thinking when he withdrew from killing Claudius the first time.à These educated guesses come from what the reader thinks, along with what critics have interpreted and written.
Thursday, October 24, 2019
Assignment About Google Essay
The question requires the student to evaluate how successful Nintendo Wii has been in meeting the needs of todayââ¬â¢s gaming through new product development. The answer here is dependent on the studentââ¬â¢s ability to analyse and evaluate the case study. The students are expected to make reference to retail marketing mix in their answer. Studentsââ¬â¢ answer should include the following or other equivalent answers: ââ¬â Considerations when developing new product strategy: i. Ongoing Corporate Planning ii. Ongoing Market Planning iii. Ongoing Technology Management iv. Opportunity Analysis/Serendipity . Market Penetration vi. Market Development vii. Product Development viii. Diversification Application of Pearsonââ¬â¢s Uncertainty Map: i. Exploratory Research ii. Development Engineering iii. Applications Engineering iv. Combining Market Opportunities Question 2 Based on the case study, how can Nintendo Wii better manage innovation as a competitive tool in the field of developmental gaming? Answer: The question requires the student to identify organization characteristics and further recommend organization changes to facilitate innovation process within Nintendo Wii. The answer here is dependent on the studentââ¬â¢s ability to analyse and give reason for choosing any relevant issues. The organization characteristics that facilitate the innovation process, studentsââ¬â¢ answer should include the following or other equivalent answers: ââ¬â i. Growth orientation ii. Vigilance and external links iii. Commitment to technology and R&D intensity iv. Acceptance of risks v. Cross function cooperation and coordination within the organization structure vi. Receptivity to change vii. Space for creativity viii. Strategy towards innovation ix. Diverse range of skills Question 1 | Percentage| | Background of the case should be clearly discussed. | 15%| 2| Feasible application should be discussed in depth| 15%| 3| Identify the multi-dimensional concept of float glass technology. | 10%| 4| Use of proper language, grammar, referencing, and acknowledgement of external sources| 10%| | | | | Total| 50%| | | | Question 2 | | 1| Explain the dilemma, recog nize the difficulties of managing uncertainty. | 20%| 2| Answers should be justified and must be logical and critical. | 20%| 3| Use of proper language, grammar, referencing, and acknowledgement of external sources| 10%| | Total| 50%| Marking Scheme
Wednesday, October 23, 2019
India of My Dreams
Essay 4 You Get All type of Essays for you. School or college no problem all types of essays are available here. * Home * Main Site * Categories * About us The India of My Dreams School Essay, The India of My Dreams Key Words and Phrases: ââ¬â past, great, today, evils, free, food, clothes, houses, education, jobs. ââ¬â rich and strong, suffering from, India of my dreams, clean and healthy, free and happy, peaceful and united, to flow with milk and honey. India was very great in the past. She was rich and strong. She has given to the world great saints, scholars, thinkers, artists and soldiers. Today her people are suffering from many evils. Among these evils are poverty, ignorance, disease, bribery, corruption, indiscipline and disunity. The India of my dreams will be free from these evils. Her people will have good food to eat. They will have fine clothes to wear. They will have nice houses to live in. They will have proper education. They will be clean and healthy. They will be free and happy. There will be jobs for all. There will be no strikes and ââ¬Ëmorchasââ¬â¢. The people will be peaceful and united. India will flow with milk and honey. all of us want India to become a respectable super power in the world. India ha a rich past. it was because of its riches, that it was invaded innumerable times and its wealth was plundered. The British rulers exploited the country. At the time of independence, the country was in turmoil, its economy had been shuttered and there was unrest all around. In sixty years since independence, the country has made tremendous progress. However, it is still for behind the developed counties of the world. India of my dreams is a peaceful, progressive, literate country free from the pangs of poverty, where every citizen feels safe and secure, where health facilities are provided top all and where the women of the country are treated with utmost dignity and respect. India, is proud of its rich past. It was because of tis riches that it was invaded innumerable times and that its wealth was plundered. The Britishers ruled India for almost two centuries and exploited the country economically. At the time of independence (August 15, 1947) the economy of the country was shattered and there was social unrest all round. However it was time for India to write its own history. A lot of progress has been made on various fronts. There have been short comings in our planning as well as its implementation. However when we notice other counties, who also achieved independence around the same time, we feel we are much better placed. Agriculture is the backbone of Indian economy. It provides employment to over 60 percent of the country's work force and it accounts for over quarter of India's gross domestic product. It also contributes substantially to export trade. However except for some pockets of development, agriculture scene in rest of the country is dismal. The farming community is generally under debt. A large number of farmers in recent years have committed suicide because of mounting economic difficulties. Industrial development plays a significant role in the growth process of the under developed counties. It helps in raising income levels and in absorbing rural surplus labour. It is believed that prior to 19th century India was a great manufacturing country. However at the time of independence the industry was in bad shape. Industrial development stared with the second five year plan. It has passed thought different phases. Many bottlenecks and red tapism came in the way of rapid development of industry. Some of the areas of concern have been addressed in the post liberation ear. The new industrial policy of July 1991 is market is needed for the growth of industry. India maintained a favorable policy towards foreign direct investment till 1967. Some preconditions and regulations were imposed from 1968 onwards. Realizing that these conditions were hampering India's industrial progress, the relaxations were made. With the economic liberalization from July 1991 onwards foreign direct investment has been encouraged and it has been allowed in many sectors. India has made its mark in ââ¬ËService Sector'. It has emerged as an important Business Process Outsourcing (BPOs and Call centers) destinations. India fortunately has a large number of well qualified English speaking population, which is needed in this kind of enterprise. India's population as per 1951 census was 36 crore. In 50 year i. e. as per 2001 census the country's population on March 31, 2001 rose to 102. 7 crores. Such rapid growth of population places a huge burden on our limited resources and limited land area. India's literacy rare as per 1951 census was less than 20 percent. In over fifty seven years it has increased to about 65 percent, which clearly indicates that even today about 35 percent of the population over 350 million people in our country are still illiterate. It is truly a sad reflection of the sate of literacy in our country. India has made rapid strides in many spheres. the economic condition of the people is better today than it was at the time of independence. We have made tremendous progress in science and technology. Our infrastructure is far better. A large number of universities, colleges and schools have been set up. Industrialization has taken place. Better health care is now available especially in urban areas. Average life span has increased. Infant mortality rate has come down. Better employment opportunities are available to the youth of the country. Means of transpiration and communication have undergone a sea change. Print and Electronic media has played a key role in creating awareness and bringing people closer. Improvement is noticeable even in provision of sports facilities. India is the third English book producing country after USA and UK. Indo-English literature is now well-developed and internationally recognized. It is able to capture many international awards like Booker price. Pulizter prize etc. Arundhati Roy, Jhumpa Lahiri, Anita Desai, Arvind Adiga etc. are some of the important names in this field. Despite all this progress which is commendable, a lot needs to be done to improve the living conditions of agricultural and industrial labor and the people working in unorganized sectors. Steps should be taken to stop crime and violence. The misguided youth of some troubled states needs to brought in the main stream. Communalism, regionalism and fundamentalism need to be curbed with a strong hand. Condition of women folk needs drastic improvement. Women empowerment is the demand of a civilized society. Equal opportunities need to be given to the girl child for education and career development. Illiteracy and poverty need to be rooted out. Self-sufficiency ought to be achieved in all spheres. Dependence on other counties should be a thing of the past. India of my drams is a country where nobody is illiterate and nobody sleeps hungry, where there is no distinction on the basis of genre, religion or caste, where justice to a common man is neither denied or deleted, where orruption in public life does not exist, where criminals can not occupy and ministerial berths nor enter legislative assemblies, where merit counts in every sphere of life, where jobs cannot be purchased, where rapists have to spend the rest of their lives behind the bars, where the intellectuals like Amartya Sen and Har Govind Khurana do not have to leave the country's shore for higher research and recognition w here the Shabad Kirtan from Gurudwaras, and Azan from Mosques, the Bhajans from Temples and chiming of the bells from churches merge and mingle and produce a harmonious, melodious, spiritual tune, loved by on MY INDIA MY DREAM ? JANA GANA MANA ADHI NAYAKA JAYAHE BHARATHA BHAGYA VIDHATHA? Yes, India? s pride never ends. It s a holy peninsular land. The great Himalayas act as strong barrier of the country. Thus India is a prestigious country. As a citizen of this beloved land I feel proud to dream about my country. I? m looking forward for a comfortable and settled life of Indians within a few years. ?JAHAN DAL DAL PAR SONE KI CHIDIYA KARTI HAIN BASERA, OH BHARAT DESH HAIN MERA? -Rajinder Krishna. Yes, that is the India of my dreams and I wish to translate these dreams into reality. What is required is our strife and struggle to annihilate the evils prevailing in our society in order to reach our goal. These evils have been inherited by a few of our own people from the British much before they left India for good, enough to award miseries, pain and insults to the masses, who continue to suffer for centuries. This is the land where ? ahimsa? was born. Even though India is a very great country with very old culture and tradition, she had not been playing a very important role in the world as she could never become independent in the real sense. But now the entire perfectionism of India has recognized. I would, therefore, like to see, in the first place, that each and every citizen, in my India, should possess a national character, which is absolutely essential to keep the banner of the country up. An erudite person should have respect for both literate and illiterate alike and the ? haves? really help the ? have-nots?. Next, India should be a place where the virulent notion of division, fragmentation or destruction through regional-national conflicts is considered an opprobrium of high degree ;the atmosphere paradisiacal with all its wonders up-to-date and the survival of its denizens , irrespective of all discriminations, absolutely necessary. Where the boundary of different states gradually ceases to exist or become truly artificial, making the national boundary healthier and stronger. Where creation of ? Gulistans? is substituted for ? Khalistans?. Today? s political ethos exhibits a very unhealthy trend. Wrong people with wrong motives are entering politics. I would like to see an India where politicians cannot inflame the spark of communal violence and riots or bamboozle voters with their duplex speeches. Every religion has impregnated its ambition with a particular shape and a specified bliss. Every religion teaches people how to love one another; we have used it to hate one another! In my India, I wouldn? t wish to see that one butchers neighbors in the name of religion and demolishes their religious places of worship. It would be a place where mere recitation of holy scripts and consecrated laws during worship would never reflect one? godliness, unless put into practice. Terrorism and militancy are raising their ugly head more than ever before. Harijans, the lowest and the most oppressed caste in India, have been successful in launching a nation- wide movement. I would love to see the people of my country free from all types of grievances, oppressions and demands. No one would ha ve to hang his head in shame. There would not be a single Indian who would not be proud of his country. While the India of my dreams would maintain amicable relations with neighboring countries, her foreign policy would be the best in the world. Even after 45 years of independence, she is still plagued by poverty, unemployment and foreign exchange trade deficit. I would, therefore, like to see India as a place where inflation and demonetization do not kill the consumers? ability to purchase. Where jobs are not deprived to even the poorest of the poor and everybody is satisfied. A healthy economy is the life-blood of a country. We would serve as a model of just such a vibrant economy- nurtured by an imaginative , innovative, liberal trade policy. The largest single source of foreign exchange for our country is tourism. I would wish this trend to continue. I would wish, in some years, India would be having the most creative entrepreneurs, the most dynamic business leaders and the sharpest financial brains. Nature has been kind to India by endowing her with the gift of abundant natural resources. Thus, in my India, there would be optimum exploitation of her resources. The machine- made articles of the world would be unable to compete with the handicrafts of our India of my dreams. Exports would be at their zenith; imports at their nadir. The quality of life cannot improve in India as long as the population keeps on ncreasing at the present alarming rate. Therefore, in my dream about India, people would be much rational and they would themselves, open-heartedly, check the population growth simply by having a child or two. Everywhere, everything would be in plenty for all. As on date, India? s is the fourth largest army, the fifth largest air force and the seventh largest navy in the world. A Pentagon report says that India is now the largest power in South Asia. I would wish to see her being ranked first in the world in all these categories and also regarded as the ? Mecca of scientific inventions and discoveries?. Also, I fantasy India as a place where cultures and civilizations are at their peak. Where child labor is unheard of and children not intentionally crippled and made to beg for personal gains of others. Where leprosy patients are not required to ask passers-by for help but provided with everything by the Government. Where men think it a sin to ask for dowry and women are treated at par with them and not harassed or burnt by in-laws. Where colleges and universities are not turned into political dense. Where the people think it ? better to spin with Penelope than dance with Helen?. Where her men and women are so perfect in all respects that they are imitated proudly by their counterparts in the rest of the world. May my India look like a fairyland to the children so that they are and all. A classes and casteless India, a country which all Indians can be truly proud of. > happy and able to weave the fabric of perfect loveliness and pulchritude. Progress is a purposive change. It can be either scientific or moral. India had tremendous progress since independence. But there are some more stages which India must cross to achieve complete progress. I wish my dreams of those progress would change India? s fate. ?HUM HONGE KAMYAB EK DIN? ââ¬â Keeping this motto in mind, let us, therefore, cry to eradicate all the evils of our society and acquire the requisite culture, discipline, attitude and habit of tolerance, goodwill and mutual respect, so that everyone of us one day, will have so clean a heart and so pure a mind that he will have a glimpse of a novel dawn, and the first of the sun, that day, will be truly golden, enough to fulfill my dreams I LOVE MY INDIA use this poem -Where The Mind is Without Fear Where the mind is without fear and the head is held high; Where knowledge is free; Where the world has not been broken up into fragments by narrow? domestic walls; Where words come out from the depth of truth; Where tireless striving stretches its arms towards perfection; Where the clear stream of reason has not lost its way into the dreary desert sand of dead habit; Where the mind is led forward by thee into ever-widening thought and actionââ¬â Into that heaven of freedom, my Father, let my country awake. ââ¬â Rabindranath Tagorerays Economic inequalities or poverty that is the root cause of several social tensions and breakdown of law and order is a thing of the past with no one being forced to suffer the pangs of hunger; every citizen is a literate adopting the norms of a small family as a way of life and contributing to the zero-growth of population; all the people lead a healthy life with epidemics being confined to the pages of history and diseases resulting from under nutrition driven out of the country; food production is enough to take care of the needs of the countryââ¬â¢s population and is exported to other countries where food production is not adequate to feed the people; the rural areas compete with urban areas in development and reduce the migration of rural poor from the villages to the cities; there is no shortage of electricity and other energy sources to keep the wheels of progress and development going; all the people have their own homes and do not feel insecure in rented houses; child labo ur is eliminated with all the children attending schools and enjoying the joy of childhood; the workers are not exploited by unscrupulous managements and are paid fair wages; legal cases are disposed off quickly and justice is speeded up; our industries compete with the multinationââ¬â¢s and give them a run for their money in the other countries; infrastructure is adequately developed to facilitate more investments in industries; domestic satellite television channels are attractive enough to wean the people away from the foreign television channels; pollution is effectively checked with industries switching over to clean or environmental-friendly technologies and vehicles checking their emissions; computers play a complementary role in common manââ¬â¢s daily activities by being an integral part of all the homes; sportsmen excel in all the international sports meets and games; religion enforces discip0line and promotes communal harmony; we become a superpower and a member of t he Security Council and are not browbeaten by any other superpower with threats of economic sanctions; and the citizens really feel proud of being Indian.
Tuesday, October 22, 2019
Themes for May Classroom Activities
Themes for May Classroom Activities Here is a list of May themes, events, and holidays with correlating activities to go with them. Use these ideas for inspiration to create your own lesson plans and activities, or use the ideas provided. Get Caught Reading Monthà The Association of American Publishers nationally launched Get Caught Reading Month to remind people how much fun it is to read. Celebrate this month by having students see how many books they can read in the month of May. The winner of the contest can receive a free book! National Physical Fitness and Sports Month Celebrate by getting active, learning about nutrition, and creating sports crafts. American Bike Month Celebrate American Bike month by having students ride their bikes to school on May 8th and learning the rules of the road and how to be safe. Childrens Book Weekà Childrens Book Week often occurs at the beginning of May, but youll need to check the dates each year. Since 1919, National Childrens Book Week has been dedicated toà encouragingà young readers to enjoy books. Celebrate this day by providingà activitiesà that will encourage your students to love reading. Teacher Appreciation Week Teacher Appreciate Week occurs in May, but the dates can vary. During this week, schools across the nation celebrate the hard work and dedication of teachers. Try a few ofà these teacher appreciation activitiesà with your students. National Postcard Weekà During the first full week of May, celebrate National Postcard Week by creating postcards and sending them to other students across the country. National Pet Week During the first full week of May, celebrate Pet Week by having students bring in a photograph of their pet to share with the class. National Police Weekà National police week occurs the calendar week during which May 15th falls. Invite a local policeman to your school, or plan a field trip to your local police station to honor this week-long celebration. National Transportation Week National Transportation Week usually occurs during the third week of May. Celebrate the community of transportation professionals by having students explore possible jobs in the transportation field. Have students research and fill out an application for a job opening in the field of their choice. Mothers Day Mothersà dayà is observed on the second Sunday of May every year. Celebrate withà Mothers Day activities, or try these last-minute lesson plans. You can also use this word list to help you create a Mothers Day poem. Memorial Day Memorial Day is celebrated on the last Monday of May each year. This is a time to celebrate and honor the soldiers that sacrificed their lives for our freedom. Honor this day by providing students with a fewà fun activities, and teach students the value of honoring the memory of those who came before us with aà Memorial Day lesson plan. May 1: May Dayà Celebrate May Day with crafts and activities. May 1:à Mother Goose Day Explore the truth about Mother Goose by reading the Real Mother Goose. May 1: Hawaiian Lei Day In 1927 Don Blanding came up with having a Hawaiian holiday that everyone can celebrate. Honor his wishes by partaking in Hawaiian traditions and learning about the culture. May 2: Holocaust Remembrance Dayà Learn about the history of the Holocaust, and read age-appropriate stories such as The Diary of Anne Frank and One Candle by Eve Bunting. May 3: Space Dayà The ultimate goal of Space Day is to promote math, science, and technology, and inspire children about the wonders of the universe. Celebrate this day by having your students partake in a few fun space-related activities to help nurture their curiosity of the universe. May 4: Star Wars Dayà This is a day to celebrate the Star Wars culture and honor the films. A fun way to celebrate this day is by having students bring in their action figures. You can use these figures as inspiration to create a writing piece. May 5: Cinco De Mayoà Celebrate this Mexican holiday by having a party, making a pinata, and making a sombrero. May 6: No Homework Dayà Your students work hard each day, celebrate this day by giving your students a No Homework Pass for the day. May 7: National Teachers Dayà Finally, a day to honor and celebrate all of the hard work teachers do! Show your appreciation for our fellow teachers by having students write a letter of appreciation to each of their teachers (art, music, physical education, etc). May 8: National School Nurses Dayà Honor your school nurse by having students create a special gift of appreciation. May 8: No Socks Day To celebrate this wacky and fun day have students create crafts out of socks, learn the history, and wear fun colored socks to school for the day. May 9: Peter Pan Day On May 9, 1960, James Barrie (the creator of Peter Pan) was born. Celebrate this day by learning about the creator James Barrie, watching the movie, reading the story, and learning the quotes. After reading his quotes have students try and come up with their own. May 14: The Start of the Lewis and Clark Expeditionà This is a great day to teach your students about Thomas Jefferson and his role in the Lewis and Clark expedition. Learn the history of the expedition, and read students the book Who Was Thomas Jefferson by Dennis Brindell Fradin and Nancy Harrison, and visit the Monticello website for photos and additional resources. May 15: National Chocolate Chip Day Whats a better way to celebrate National Chocolate Chip Day than to bake some cookies with your students! For some added fun, try this chocolate bar math lesson. May 16: Wear Purple for Peace Dayà Help make the world a better place by having all students wear purple for peace day. May 18: Armed Forces Dayà Pay tribute to the men and women who serve the United States armed forces by having students write a thank you letter to someone in your local armed forces. May 20: Weights and Measures Day On May 20, 1875, an International treaty was signed to establish an international branch of weights and measures. Celebrate this day with your students by measuring objects, learning about volume, and exploringà non-standard measures. May 23: Lucky Penny Dayà Lucky Penny Day is celebrated to reinforce the theory that if you find a penny and pick it up, you will have good luck. Celebrate this fun day with your students by creating a penny craft, counting and sorting pennies, or using pennies to graph Another fun idea is to give students the writing prompt, Once I found a lucky penny and when I picked it up... May 24: Morse Code Dayà On May 24, 1844, the first Morse code message was sent. Celebrate this day by teaching your students Morse Code. The students will love the secretiveness of it all. May 29: Paper Clip Dayà In 1899 Johan Vaaler, a Norwegian inventor invented the paper clip. Honor this amazing little wire by having students come up with a new way to use it. May 29: John F. Kennedys Birthdayà John F. Kennedy was one of the most beloved United States Presidents of our time. Honor this remarkable man and all of his accomplishments by having students create a KWL Chart, then read your students his biography, called Who Was John F. Kennedy? by Yona Zeldis McDonough. May 31:à World No Tobacco Dayà World No Tobacco Day is a day to reinforce and highlight the health risks associated with tobacco use. Take time out on this day to stress the importance of why students should not smoke.
Monday, October 21, 2019
Joe Magnarelli at Smalls Jazz Club
Joe Magnarelli at Smalls Jazz Club Free Online Research Papers On Thursday, February 13th, I went to a club performance at Smalls Jazz Club on 183 W. 10th Street to hear Joe Magnarelli on trumpet play a set with a pianist, bassist, and percussionist. The set lasted over an hour and was appreciated by a large audience crammed into the tiny basement room. The songs performed were Mr. Mags, Waltz for Aunt Marie, Rubyââ¬â¢s Weekend, Youââ¬â¢ve Change, and Home Changed. My overall impression was that the ensemble, particularly Joe Magnarelli, was fantastic but that I had trouble understanding what was going on in the music. The style of the group was more modern than what we have studied in class, so I did not know how to classify it or understand it fully. I did notice, however, that they used a contemporary version of the classic New Orleans style by using structured yet improvised counterpoint that was more dissonant and jagged than that from the early 20th century. In terms of the ensemble, Joe Magnarelli was clearly the leader of the group, as he stood in front of the other three members and always took the first and last solos of each piece. The other three players, however, each had their turn at taking solos, although the pianist clearly had more solos than the bassist and percu ssionist. I assumed that this allotment of solos occurred because the bass and percussion comprised the rhythm section, which by nature does not give many solos, while the piano and trumpet were the melody players. The group, for the most part, alternated between faster, upbeat songs and slower, creamier songs. It was during the upbeat songs that I noticed the use of the New Orleans counterpoint. I immediately, however, took a preference to the slower pieces. I felt that the fast songs were too ââ¬Å"busyâ⬠sounding (New Orleans style gone crazy), with each musicianââ¬â¢s part sounding so different from the rest that any cohesiveness within the group was hard to depict. I also felt that the balance in the upbeat numbers was a little percussion-heavy, where the clanging of the hihat pierced through the rest of the ensemble, thus distracting the listener from the other parts. Furthermore, it was harder to pick out melodies and themes in the faster songs than it was in the slower songs, so I tended to understand the forms of the slower songs better. I particularly appreciated the second song, ââ¬Å"Waltz for Aunt Marie.â⬠It was a soulful tune that allowed Joe Magnarelli to highlight his smooth, tender tone on the trumpet, which was a beautiful contrast to his brassier tone used in the faster songs. One part of the song that struck me was its tag: Magnarelli took an unaccompanied solo mainly consisting of an ascending scale and then ended with the group on the tonic of the key of the piece. This ending surprised me, for I usually expect a jazz number to end on an unpredictable note- i.e., anything but the tonic. I really appreciated that deviance from standard jazz practice, where a little classical influence was a nice touch to the piece. I spoke to Joe Magnarelli after the set to compliment on his performance, particularly on his beautiful sound in the slower tunes. I then asked him how it felt to create such beautiful moments while his audience chatted away to such an extent that the people could not have possibly appreciated the sophisticated mood of the song. I asked him this because during the beautiful end of ââ¬Å"Waltz for Aunt Marie,â⬠I had trouble focusing on the music because of all the noise around me, thus rendering me quite agitated. I mentioned to him that I am a classical musician, so I expect complete silence when I perform or attend a concert, and I asked him what he thought of the difference in protocol between the two types of music. He responded that he cares only that his audience has a good time, so he does not want to appear too anal about the noise level in the club. I asked if he would ever tell an audience in the middle of set quiet down if the people were too noisy, and he said no, t hat jazz creates a more relaxed atmosphere than classical music and that noise level is something jazz musicians must simply deal with. He was so nice and giving of his time that I was really thrilled to talk to him. He even asked for my name, and when I said Laura, he mentioned the song ââ¬Å"Lauraâ⬠and said he would play it for me if I ever came to hear him again. I was really touched by his kindness; it made the whole evening worthwhile. It also made me understand the love that exists within jazz, where the musicians play and improvise from their hearts and love the music despite any surrounding circumstances. Sometimes I do not have that same impression about classical music. I cannot help to feel, however, that it is wrong to treat jazz as background music, such as many of the audience members at Smalls did that night. Perhaps people go to Smalls for its atmosphere and not necessarily for the music itself. I am not against the atmosphere that a small, cozy, jazz club creates; however, I feel the music should always come first and that that rule should hold for both classical music and jazz. Research Papers on Joe Magnarelli at Smalls Jazz ClubThe Fifth HorsemanHip-Hop is ArtThe Hockey GameWhere Wild and West MeetNever Been Kicked Out of a Place This Nice19 Century Society: A Deeply Divided EraIncorporating Risk and Uncertainty Factor in CapitalThe Spring and AutumnEffects of Television Violence on ChildrenQuebec and Canada
Sunday, October 20, 2019
History of the Quiché Maya - Popol Vuh
History of the Quichà © Maya - Popol Vuh The Popol Vuh (Council Book or Council Papers) is the most important sacred book of the Quichà ©; (or Kiche) Maya of the Guatemalan Highlands. The Popol Vuh is an important text for understanding Late Postclassic and Early Colonial Maya religion, myth, and history, but also because it also offers interesting glimpses into Classic Period beliefs. History of the Text The surviving text of the Popol Vuh was not written in Mayan hieroglyphics, but rather is a transliteration into European script written between 1554-1556 by someone said to have been a Quichà © nobleman. Between 1701-1703, the Spanish friar Francisco Ximenez found that version where he was stationed in Chichicastenango, copied it and translated the document into Spanish. Ximenez translation is currently stored in the Newberry Library of Chicago. There are numerous versions of the Popol Vuh in translations in various languages: the best known in English is that of Mayanist Dennis Tedlock, originally published in 1985; Low et al. (1992) compared the various English versions available in 1992 and remarked that Tedlock immersed himself in the Mayan point of view as much as he could, but by and largely picked prose rather than the poetry of the original. The Content of the Popol Vuh Now it still ripples, now it still murmurs, ripples, it still sighs, still hums and is empty under the sky (from Tedlocks 3rd edition, 1996, describing the primordial world before creation) The Popol Vuh is a narrative of the cosmogony, history, and traditions of the Kiche Maya before the Spanish conquest in 1541. That narrative is presented in three parts. The first part talks about the creation of the world and its first inhabitants; the second, probably the most famous, narrates the story of the Hero Twins, a couple of semi-gods; and the third part is the story of the Quichà © noble family dynasties. Creation Myth According to the Popol Vuh myth, at the beginning of the world, there were only the two creator gods: Gucumatz and Tepeu. These gods decided to create earth out of the primordial sea. Once the earth was created, the gods populated it with animals, but they soon realized that animals were unable to speak and therefore could not worship them. For this reason, the gods created humans and had the animals role relegated to food for humans. This generation of humans was made out of mud, and so were weak and were soon destroyed. As a third attempt, the gods created men from wood and women from reeds. These people populated the world and procreated, but they soon forgot their gods and were punished with a flood. The few who survived were transformed into monkeys. Finally, the gods decided to mold mankind from maize. This generation, which includes the present human race, is able to worship and nourish the gods. In the narration of the Popol Vuh, the creation of the people of corn is preceded by the story of the Hero Twins. The Hero Twins Story The Hero Twins, Hunahpu, and Xbalanque were the sons of Hun Hunahpu and an underworld goddess named Xquic. According to the myth, Hun Hunahpu and his twin brother Vucub Hunahpu were convinced by the lords of the underworld to play a ball game with them. They were defeated and sacrificed, and the head of Hun Hunahpu was placed on a gourd tree. Xquic escaped from the underworld and was impregnated by the blood dripping from Hun Hunahpuââ¬â¢s head and gave birth to the second generation of hero twins, Hunahpu and Xbalanque. Hunahpu and Xbalanque lived on the earth with their grandmother, the mother of the first Hero Twins, and became great ballplayers. One day, as had happened to their father, they were invited to play a ball game with the Lords of Xibalba, the underworld, but unlike their father, they were not defeated and stood all the tests and tricks posted by the underworld gods. With a final trick, they managed to kill the Xibalba lords and to revive their father and uncle. Hunahpu and Xbalanque then reached the sky where they became the sun and moon, whereas Hun Hunahpu became the god of corn, who emerges every yearà from the earth to give life to the people. The Origins of the Quichà © Dynasties The final part of the Popol Vuh narrates the story of the first people created from corn by the ancestral couple, Gucumatz and Tepeu. Among these were the founders of the Quichà © noble dynasties. They were able to praise the gods and wandered the world until they reached a mythical place where they could receive the gods into sacred bundles and take them home. The book closes with the list of the Quichà © lineages up until the 16th century. How Old is the Popol Vuh? Although early scholars believed that the living Maya had no recollection of the Popol Vuh, some groups retain considerable knowledge of the stories, and new data have led most Mayanists to accept that some form of the Popol Vuh has been central to the Maya religion at least since the Maya Late Classic Period. Some scholars such as Prudence Rice have argued for a much older date. Elements of the narrative in the Popol Vuh argues Rice, appear to predate the late Archaic separation of language families and calendars. Further, the tale of the one-legged ophidian supernatural who is associated with rain, lightning, life, and creation is associated with Maya kings and dynastic legitimacy throughout their history. Updated byà K. Kris Hirst Sources Dictionary of Archaeology.Carlsen RS, and Prechtel M. 1991. The Flowering of the Dead: An Interpretation of Highland Maya Culture. Man 26(1):23-42.Knapp BL. 1997. The Popol Vuh: Primordial Mother Participates in the Creation. Confluencia 12(2):31-48.Low D, Morley S, Goetz D, Recinos A, xe, Edmonson M, and Tedlock D. 1992. A Comparison of English translations of a Mayan text, the Popol Vuh. Studies in American Indian Literatures 4(2/3):12-34.Miller ME, and Taube K. 1997. An Illustrated Dictionary of The Gods and Symbols of Ancient Mexico and the Maya. London: Thames and Hudson.Paulinyi Z. 2014. The butterfly bird god and his myth at Teotihuacan.à Ancient Mesoamerica 25(01):29-48.Rice PM. 2012. Continuities in Maya political rhetoric: Kawiils, katuns, and kennings.à Ancient Mesoamerica 23(01):103-114.Sharer RJ. 2006. The Ancient Maya. Stanford, California: Stanford University Press.Tedlock D. 1982. Reading the Popol Vuh over the shoulder of a diviner and finding out whats so funny. Conjunctions 3:176-185. Tedlock D. 1996. The Popol Vuh: Definitive Edition of the Maya Book of the Dawn of Life and the Glories of Gods and Kings. New York: Touchstone.Woodruff JM. 2011. Ma(r)king Popol Vuh.à Romance Notes 51(1):97-106.
Saturday, October 19, 2019
American Political Thoughts Essay Example | Topics and Well Written Essays - 2500 words
American Political Thoughts - Essay Example It is imperative that both the great depression that occurred in 1930s and the late 2000s great recession completely draws the difference between American presidents especially Franklin Roosevelt, George Bush and Barack Obama. The two economic crises caused banking-financial crisis, great surge in unemployment, and severe stock market slump. It is imperious to understand that in all the cases, both the presidents pledged to eliminate the economic crises and provide a state of calm within America. The paper explores how the how the three presidents managed to retain economic crisis during their era. In addition, the paper analyses significant similarities and differences in the policies employed by each administration in maintaining economic levels. The great depression remained as the historic economic crisis in western industrialized countries that started from 1929 and ended in 1940. The depression remained as the longest economic crises in American history marked by significant decline in investment, rising levels of unemployment, and decrease in living standards of American people. The great economic downtown resulted from Wall Street cash crash and the great drought that affected agricultural activities on the south (Skocpol and Jacobs 15). The great depression started during President Hoover era and proceed during Franklin Roosevelt presidency. During the start of great depression in 1929, American people blamed President Herbert Hoover for his policies that may have resulted into economic down town. When Franklin D. Roosevelt (FDR) won the 1932 presidential elections, he began the longest journey of recovering the depressed economy. Roosevelt immediately assured American people of the possibility of economic recovery and then initiated the New Deal policies aimed at normalizing the depression. Franklin D Roosevelt became the president of United States in 1932 and succeeded Herbert Hoover. The beginning of his
Friday, October 18, 2019
Weekly ass. #9 Essay Example | Topics and Well Written Essays - 250 words - 1
Weekly ass. #9 - Essay Example We wanted someone who could supply the linen to us at a considerably cheaper price. Therefore, we are offering the contract to a candidate who is supplying the linen at a price that is within our range. However, the good work that you have been doing is not forgettable and we are keeping your tender in our system. If at any time you feel that you can review the range at which you supply the materials to us, you will be among the first to be considered if there is any other opportunity for tenders. There are many other products that Anytown General Hospital needs and you can present your tender for supplies in any other department. We are starting classes for free disaster preparedness. We need suppliers for some of the products that we will be using; you can check on our website for details and present your tender if you would wish to bid. On behalf of Anytown General Hospital, I thank you for your time, interest, effort and continual cooperation when you worked with us. I wish you the best in your business proceedings, and if you have any questions regarding the same issue, please do not hesitate to contact us through
Informative writing Essay Example | Topics and Well Written Essays - 750 words
Informative writing - Essay Example These include the basis of meeting and discussing with clients as to what the exact requirements are, drawing up a brief as to what should be done, and finding out creative solutions for the clients which is one Herculean task. The field of advertising is renowned because it creates a spell for each and everyone yet it does not reveal the complexities that remain within its own folds. It lets the people to enjoy the different shades of beauty, fashion and product advertising but does not tell much about what goes on behind the scenes and how difficult it is to convince the clients to begin with. What is even more distressing to know is that at times the varied advertising agencies are taken for a ride by the clients. They are not given their dues for a long time which essentially means that the wages and salaries of employees are put on hold. Even though advertising looks great from the outside, its inner side is very horrific to state the least. People are made to work at odd hours of the day and even night. The clients can absolutely rule the roost because they care less about the ones who work for them and get their work done. This is in essence a form of abuse that is being committed by the clients as and when they wish to exploit. As advertising comprises of many diversified business avenues as well, most noteworthy being public relations, event management, direct selling and so on, it covers quite a few areas which is a headache for the advertising agencies and their personnel. The advertising agencies therefore recruit individuals who can work for long hours, have it in them to handle pressure at odd times of the day, can interact with all sorts of clients, are creative on most of the occasions, and do not say no ever to any one. These are some of the salient points which go into manufacturing an advertising genius and this is the reason he is paid handsomely but that too after a long period of time. The initial years are always the most difficult ones i n terms of work-life balance and salary issues. Hence one when someone suggests that advertising is a leisure field and it makes the people feel excited, they are completely in the wrong because it does not happen so in entirety. There are a number of reasons which state how advertising will have to come out in the open with its real face. In line with this discussion it is significant to comprehend that advertising gives its own people a tough time. The consumers are always misled at times which are somewhat of a shambles for the entire field under discussion. The misconceptions regarding advertising are immensely drawn up and it is about time that these are resolved to produce high level linkages between the people and the ones who are advertising them in the first place. The element of consumerism becomes apparent within the understanding of advertising and how it is making its mark within the related scheme of things. In the end, it would be appropriate to state that advertising is a very difficult field for beginners. They must be mentally very tough to adhere to the rigorous routines and work pressures that would come their way. It would make them stand in a league of their own if devotion and patience remain the keys. Therefore advertising is a field that has a number of misconceptions attached with it and it is very apt to state here that these must be shed off for the betterment of the youngsters who want to join this
Thursday, October 17, 2019
Plz make my college app perfect Essay Example | Topics and Well Written Essays - 500 words
Plz make my college app perfect - Essay Example I find this combination moving due to the depth of inspiration that I can derive from them. My faith and belief ultimately leads me to create how things I wanted to me, and religion which is a repository of countless arts forms of masters, both old and new, where manââ¬â¢s genius in art was and still is best illustrated is an excellent source of inspiration to draw upon. From these two potent forces, I then create my own art form through my paint that breathe life on my subjects be it on my canvass or other mediums that inspiration may find suitable. My artworks are mostly made of patterns which I use to expand my old way of doing a mystery piece by mixing my pattern design with a portrait. This method brings out a very powerful impression on my portraits that impresses a strong emotion. So far, it is also the best method that I have tried that could show more of my idea about ideal beauty. I also do it against the backdrop of many different cultures where I borrow what I feel to be best suited for my portrait to come up with unimaginable great result. I think many artists experience that feeling of being deeply immersed in their paintings that they lose track of time whenever they are engage with their work. Such is my case. I am very meticulous to details and spend a great deal time to be able to portray what I have in mind and I do not stop until I feel it is right. Being faithful to that idea of the ideal of giving truth to beauty is what animates me in my studio for hours as I explore the province of dreams through my artworks. I feel like that if I stop short of what I feel and believe is right, I am betraying my art. Such, I pursue it until I found the truth and had them manifested in my artwork. I do not mine the countless hours, days, even weeks that I will spend to achieve the ideal in my artworks. I am willing to do it again and again knowing that the opportunity to touch the human
Managing Human Resources Bachelor Essay Example | Topics and Well Written Essays - 500 words
Managing Human Resources Bachelor - Essay Example The following topics that NL&C needs to include in a Comprehensive Management Training Program are as follows: Seminar Workshop on Recruitment of Employees, Orientation on the Employees Benefits from the Company's Progressive Profit-Sharing Plan, Capability Enhancement Training for Employees in the Management Positions, Orientation Workshop on Collective Bargaining, Harmonization and Team Building Activities and lastly, Leadership Training. Since, as the Human Resources Director, I just joined the organization two months ago, I will make use of the available data, observations and on several areas noticed from the first couple of months with NL&C that need development or redesign in assisting the would-be resource persons in coming up with training modules for each components that are customized to the NL&C. The Human Resources Department was established by the president since the company has grown to the point of needing that department. Hence, the above topics are brainstormed and conceptualized. The Comprehen
Wednesday, October 16, 2019
Plz make my college app perfect Essay Example | Topics and Well Written Essays - 500 words
Plz make my college app perfect - Essay Example I find this combination moving due to the depth of inspiration that I can derive from them. My faith and belief ultimately leads me to create how things I wanted to me, and religion which is a repository of countless arts forms of masters, both old and new, where manââ¬â¢s genius in art was and still is best illustrated is an excellent source of inspiration to draw upon. From these two potent forces, I then create my own art form through my paint that breathe life on my subjects be it on my canvass or other mediums that inspiration may find suitable. My artworks are mostly made of patterns which I use to expand my old way of doing a mystery piece by mixing my pattern design with a portrait. This method brings out a very powerful impression on my portraits that impresses a strong emotion. So far, it is also the best method that I have tried that could show more of my idea about ideal beauty. I also do it against the backdrop of many different cultures where I borrow what I feel to be best suited for my portrait to come up with unimaginable great result. I think many artists experience that feeling of being deeply immersed in their paintings that they lose track of time whenever they are engage with their work. Such is my case. I am very meticulous to details and spend a great deal time to be able to portray what I have in mind and I do not stop until I feel it is right. Being faithful to that idea of the ideal of giving truth to beauty is what animates me in my studio for hours as I explore the province of dreams through my artworks. I feel like that if I stop short of what I feel and believe is right, I am betraying my art. Such, I pursue it until I found the truth and had them manifested in my artwork. I do not mine the countless hours, days, even weeks that I will spend to achieve the ideal in my artworks. I am willing to do it again and again knowing that the opportunity to touch the human
Tuesday, October 15, 2019
Inquiry Based Project for Literacy Learning Assignment
Inquiry Based Project for Literacy Learning - Assignment Example â⬠¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦ 11 Reference listâ⬠¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦Ã¢â¬ ¦ 13 Abstract According to Talay-Ongan, literacy learning is a continuous process that needs consistency to have apt performance. This is especially so when it comes to youngsters that need to grasp enough information in accordance to learning. Therefore, children between the ages of five to eight have to be given ample assistance in coming up with a developed learning. The person in control of their learning, especially teachers are to encompass all developmental approach to students to make a perfect learning practice. This will assist the students at this tender age to amass enough opportunity to make better educational standards. The use of balanced approach to development is a system that has been noted to reflect plausible results to the concerned students. The students end up having a balanced learning experience that institutes greater learning, especially when the children are growing up (Talay-Ongan, 2004). This shows why many students with balanced developments during their initial learning have better performance as compared to students with reduced keenness during their initial learning stages. Therefore, it is a prudent approach to design a succinct development project that could be used with the children at their tender ages. This will assist in amassing enough knowledge that could be used in the course of their learning. In addition to this, appraising the developmental project is a point that will reflect a better approach to educational standards. 1.0 Theoretical Perspectives and Rationale Theoretical perspective and rationales are used to ensure there is better performance in accordance to the learners. They are used to measure the performance and effectiveness of the learning in accordance to the youngsters. In this design, the decision was to engage in reading of different texts during the learning. The language has a variety of phonics used to make a difference between the sounds and the letters. This is the initial stage that should be mastered by children during their early ages of growing. Therefore, there is need to have a reelection of the stated phonics, in every language. Though some languages have the same phonics with different pronunciation, banking on the ostensible language is an appropriate measure. This states why people from different continents spell and read the same word in a totally different pronunciation (Talay-Ongan, 2004). This is basically due to their induction in the phonics of their basic language. It is widely known as a
Monday, October 14, 2019
Sustainable development Essay Example for Free
Sustainable development Essay Introduction: Without a shadow of doubt, one of the problems facing todayââ¬â¢s China is water pollution. Maybe you will ask, how to define water pollution? Why we will say the water pollution problem in China is so serious? Actually, there are many different ways to measure water pollution. For example, use instrument to test the safety level of water or by using the ph-value to test whether it meets or exceeds the national standard or not. However, we are not professionals. Therefore, today I will just tell you two simple ways. First, by chemical indicators, we can take the water sample and measure the concentrations of chemicals that it contains. If the chemicals are dangerous or the concentrations are too great, that means the water is polluted. Second, by biological indicators, we can examine living things that water will support. If living things can live in the water that means the water quality is still acceptable. However, if the living things canââ¬â¢t live, the water quality is so poor. These simple ways can test whether the water is polluted or not. Causes: There are two main reasons that cause water pollution. First is the industry. In recent years, the rapid development of industrial and urban areas, and changes in agricultural practices. The discharge of waste from industries. The owners think that rivers and oceans are convenient places for them to dump their waste material. However, they did not concern these waste contains toxic substances that may cause damage to the river and lake and also, it is harmful for humans and aquatic animals. Second, for the public, too many selfish and lazy members of the public have immediate satisfaction. This poor civic spirit, a mind-your-own-business, non-confrontational culture make the situation worse. In China, all you have to do is step outside to see evidence of a lack of public hygiene. One popular pastime is littering. The ââ¬Å"expertâ⬠litterer refuses to put hisà cigarette butt, used tissue, or fish-ball stick in a bin, even if there is one only 3 steps away. It is not surprising that one day, we will live with sewage-strewn beaches and dead rivers. All in all, because the discharge of waste from industries and selfish citizens and weak enforcement of littering laws and government complicity in pollution all combine to make prospects for improvement bleak. Impact on Economic Aspect, Case Study: Concerning pollution of river, algae bloom on Lake Tai has been the concrete example showing the negative impact of unsustainable practices on economic development in recent years. And the government needed to spend huge sum to revamp the situation. Taihu is third largest lake in China, covering an area of 2400 km2. It is the major source of water to Shanghai, Suzhou, Changzhou and Wuxi, Hangjiahu Plain. As the Chinese saying goes, those living on a mountain live off the mountain; those living near the water live off the water. Therefore, the river becomes a major source of income to the local as well. Aquaculture industry, hairy crabs industry in particular, is thriving there. However, the mis-use of chemical substances around Taihu has led an ecological disaster since the 80s. Apart from the industrialization and influx of population of 20 million people along Taihu, development of agriculture and aquaculture contributed to excessive nutrients inside the river. According to Liang and He (2012), the organic pollutant in water sharply rose from 1% in 1987 to 29.18% in 1994. A proliferation of blue algae happens every now and then because of eutrophication in river. Netted enclosures used in Taihu As Qin discovers (as cited in wang, 2007) that excessive amount of bait led to eutrophication of river. Compared with that of river, the water sample ofà breeding grounds contained higher concentration of ammonia and nitrogen. Plus, the netted enclosures deterred the aquatic plants from purifying the water. And the slower flow of water supported accumulation of chemical. Hence, the Jiangsu government annually invested RMB 2 billion for management of Taihu since the massive outburst in 2007. And 2.8 million tons of algae were removed between 2007 and 2011 (Liang and He, 2012). According to Wu and Cai (2007), the Chinese government strictly controlled artificial breeding space then. The size of breeding grounds was prohibited to expand and limited to meet scientifically sound standard in Taihu, Chaohu and Dianchi. It was projected that the size of breeding grounds would significantly drop from 81 thousand to 32 thousand hectares in 2008, coupled with the output volume of 8 thousand tons. The sharp decrease in harvest by 10 thousand tons drove price rise. In fact, besides the environment, the local government protected the livelihood of those crab farmers. After the implementation of projects, the number of hairy crab breeders was estimated to decrease to 1500 along Yangchenhu. Hence, provision of monetary compensation aside, these primary producers received knowledge transfer to shift to value chain of crab products. In short, rather than stable growth of GDP from the heavily polluted source, the local government would like to achieve long-term growth by restoring ecological balance and upgrading the development of cities. Plus, the farming and horticulture industry were disallowed to develop within 1 kilometer of peak discharge of river to avoid soil contamination, in turn water pollution of river. Finally, according to ââ¬Å"Harvest Hairy Crab in Taihu, Output and Price rose by 30%â⬠(2011), the quality of hairy crab along Taihu were better than before because of better water quality and limited production. And the Trophic state index dropped to 60.8 in 2011, compared to 62 in 2007 (Ding, 2012). Plus, as Xu reports (2008) that, despite smaller size of breeding ground of hairy crab, the better freshwater favor survival of crab seed which wouldà not lead to a dramatic drop in output but maintain freshness of produce. In conclusion, there is a long way to complete restoration of Taihu because of high accumulation of chemical substances from human activities nearby. However, the human-induced eutrophication of river can be controlled by the planning and monitoring of the local governments. Meanwhile, they can lay more effort into developing high-price hormone-free crabs to meet greater and greater demand over the world while maintaining sustainability of river for next generation of Taihu. Our future: When considering our future, it seems we have two choices. We can passively let the future happen and live with dead rivers or alternatively we can actively change our future by taking specific steps like work together to keep the water clean so the living things and people remain healthy. We benefit, or suffer, from the decisions made by us today. For me, of course, I will choose the latter one. By doing so, there are three aspects that can do better. First, for education. I think no one will disagree that the success of government education programs is a long term proposition. We need to make people aware of the water pollution problem and its impact. Educators can teach people to clean up their act and organize activities like community beach-cleaning sessions. Also, some concern groups can work with media like television channels or short movies to produce water management programs to promote public education. Education is the key. Positive public action can make a great change. Second, for the laws. Recently, China has enacted regulations and laws to reduce water pollution. However, I think the government needs to punish the offenders. New laws, higher fines, stricter enforcement are indispensable. They can force people and companies to clean up their act. Third, for the economy. Since a large amount of money spent on treating the polluted water. Many environmental experts agree ââ¬Å"polluter pays principleâ⬠à that means polluter needs to pay for the damage done to the natural environment. Therefore, they may fear that they need to pay more so they try to think some ways that cause less pollution. Last but not least, according to GREENPEACE, ââ¬Å"25% of Chinas seven largest river systems, which include the Yangtze River, the Yellow River, and the Pearl River, fails to provide water which is suitable for irrigation and is considered highly polluted. In addition, 30% of the Chinas rivers and 25% of her coastal areas are considered highly polluted. If one were to take all of Chinas clean water supply and share it evenly with the population, the amount each person would get would be miniscule.1â⬠Therefore, to live better or not, everyone is the director. Positive action can change our future. Just start from today, tackle water pollution before it is too late.
Sunday, October 13, 2019
Cloud Point Extraction Experiment
Cloud Point Extraction Experiment Bromothymol blue (also known as bromothymol sulfone phthalein, BTB) (Figure 2.1.1) is a pH indicator (yellow at pH 6.0 and blue at pH 7.6). Its chemical name is: 4,40-(1,1-dioxido-3H-2,1-benzoxathiole-3,3-diyl)bis(2-bromo-6-isopropyl-3-methylphenol (The Merck Index, 13th edition, 2007)[1]. pKa of BTB is 7.1. This dye is the most appropriate pH indicator dye in physiological tissue and also used in the investigation of the interaction of lipid with protein (Puschett and Rao 1991; Gorbenko 1998; Sotomayor et al. 1998)[2,3,4]. It is widely applied in biomedical, biological, and chemical engineering applications (Schegg and Baldini 1986; Ibarra and Olivares-Perez 2002)[5,6]. BTB in protonated or deprotonated form is yellow or blue in color, respectively, while its solution is bluish green in neutral solution. It is sometimes used to define cell walls or nuclei under the microscope. BTB is mostly used for the evaluation and estimation of the pH of pools and fish tanks and the determinatio n of the presence of carbonic acid in liquid. There are several treatment procedures for dyes from waste materials, including adsorption (Nandi, Goswami, and Purkait 2009)[8], coagulationââ¬âflocculation, oxidationââ¬âozonation, reverse osmosis, membrane filtration, biological degradation, and electrochemical processes (Shen et al. 2001; Kim et al. 2004; Chatterjee, Lee, and Woo 2010)[9,10,11]. 2.1.2 EXPERIMENTAL 2.1.2.1 Materials: All the solutions were prepared with double-distilled water. 2.1.2.1.1 Triton X ââ¬â 100 (0.1M): Triton X-100 was purchased from Qualigens Analytical grade. The TX-100 was cleared of any low-boiling impurities by exposure to vaccum for 3h at 700C following the procedure given by Kumar and Balasubrahmanium[19]. 31.4 g of TX-100 liquid is dissolved 500 ml volumetric flask and made up to the mark to obtain 0.1 mol/dm3 solution. The critical micellar concentration and Cloud point of TX-100 are 2.8Ãâ"10âËâ4 [20] 65à ¢-à ¦C [21] respectively. 2.1.2.1.2 Bromothymol Blue (BTB) : 1.0 g of BTB dye Merck India was dissolved in 5.0 ml of ethanol (99.8%) for dissolution then dilution are made with double distilled water into a 1000 ml volumetric flask up to the mark to obtain an concentration of 1000 mg/dm3(Babak Samiey, Kamal Alizadeh et.al 2004)[22]. In order to avoid fading stock solution was wrapped black color paper. The working solutions of BTB were prepared by appropriate dilutions of the stock solution immediately prior to their use. 2.1.2.1.3 Acetic acid (0.5M). 28.5 ml glacial acetic acid (A.R.grade) Qualigens was diluted with distilled water in a 1000 ml volumetric flask to give 0.5M Acetic acid solution. The solution obtained was diluted to required concentration and standardized as per the procedure (Vogel et. al. 1989)[23] with standard NaOH solution. 2.1.2.1.4 Sodium acetate (0.5M): 13.6 g sodiumacetate.trihydrate, (CH3COONa.3H2O) of Analytical grade Qualigens is dissolved in 100 ml volumetric flask and made up to the mark (Vogel et. al. 1978)[24]. 2.1.2.1.5 NaCl (0.1M): 2.922 g pure dry salt of sodiumchloride of analytical grade Qualigens is weighing out and dissolved in 500 ml volumetric flask to give 0.1M NaCl solution(Vogel et. al. 1989)[25]. 2.1.2.1.6 Na2SO4 (0.5M): 16.1 g of sodiumsulphate decahydrate,(Na2SO4.10H2O) A.R.grade from Merck (India), is dissolved in 100 ml volumetric flask and made up to the mark to give 0.5M Na2SO4 solution(Vogel et. al. 1989)[26]. 2.1.2.1.7 KH2PO4(1.0M): 34.02 g of KH2PO4 of Analytical grade Qualigens is dissolved in 250 ml volumetric flask and made up to the mark (Vogel et. al. 1978)[27]. 2.1.2.1.8 Na2HPO4 (1.0M): A.R. grade disodium hydrogen phosphate, Na2HPO4.2H2O, is taken in porcelain crucible and heated until no more water is liberated. Then 17.8 g of this cold residue is taken in 100 ml volumetric flask and made up to the make to give 1.0 M of Na2HPO4 solution (Vogel et. al. 1978)[28]. The reagent is prepared freshly each time. 2.1.2.1.9 Buffer solution of pH4.0(à ±0.05): 5 ml of 4M sodium acetate (A.R. grade) Qualigens and 20 ml of 4M acetic acid (A.R. grade) Qualigens are mixed in an 100ml volumetric flask and made up to the mark which has resultant pH of 4.0(à ±0.05) (Vogel et. al. 1989)[29] . 2.1.2.1.10 Buffer solution of pH5.0(à ±0.05):: 17.5 ml of 4M sodium acetate (A.R. grade) Qualigens and 10 ml of 4M acetic acid (A.R. grade) Qualigens are mixed in an 100ml volumetric flask and made up to the mark which has resultant pH of 5.0(à ±0.05) (Vogel et. al. 1989)[30] . 2.1.2.1.11 Buffer solution of pH6.0(à ±0.05): 13.2 ml of1M KH2PO4 (A.R.grade) Qualigens and 86.8 ml of 1M Na2HPO4 (A.R.grade) Qualigens are mixed in 100ml volumetric flask which has resultant pH of 6.0(à ±0.05) (Vogel et. al. 1989)[31]. 2.1.2.1.12 Buffer solution of pH7.0(à ±0.05): 61.5 ml of 1M KH2PO4 (A.R.grade) Qualigens and 38.5 ml of 1M Na2HPO4 (A.R.grade) Qualigens are mixed in 100ml volumetric flask which has resultant pH of 7.0(à ±0.05) (Vogel et. al. 1989)[31]. 2.1.2.1.13 Buffer solution of pH8.0(à ±0.05): 94.0 ml of 1M KH2PO4 (A.R.grade) Qualigens and 6.0 ml of 1M Na2HPO4 (A.R.grade) Qualigens are mixed in 100ml volumetric flask which has resultant pH of 8.0(à ±0.05) (Vogel et. al. 1989)[31]. 2.1.2.1.14 Buffer solution of pH9.2(à ±0.05): 1.905g of Na2B4O7.10.H2O of (A.R.grade) Qualigens is dissolved in 100ml volumetric flask and made up to the mark to obtain 0.05 M of borax solution.The resultant pH of the solution is 9.2(à ±0.05) (Vogel et. al. 1989)[32]. 2.1.2.2 Methodology for cloud point extraction: 2.1.2.2.1 Procedure: The cloud point temperature was determined by literature method reported by Carvalho et al. [33]. This is based on the ââ¬Ëvisual observation of the separation of phasesââ¬â¢ in the micellar solution. The solution was heated gradually in the water bath until turbidity appeared. To verify the results, the opposite process was carried out by cooling gradually with constant stirring and the cloud point was considered as the temperature at which the solution became clear. The reported value was the average of these two determinations; in most cases, these two temperatures were identical, within + 0.5oC. Cloud point extraction experiment was conducted by using a 10 ml centrifuge tube with a screw cap containing different concentrations of Triton X-100 and BTB and sonicated for 2 minutes for proper mixing. The solution is heated up to 80Ãâ¹Ã
¡C in a thermostatic temperature bath for 20 min. The turbid solution was then centrifuged at 3500 rpm for 5 min and cooled in an ice bath for 2 minutes in order to separate the phases. Both the phases are separated and the volumes of surfactant rich phase (coacervate phase) and dilute phases were measured. Average of three determinations is reported in all cases. The concentration of dye in both the phases has been measured by using PerkinElmer lamda-25 UV-Visible spectrophotometer. In order to determine the influence of the reagents added to the surfactant phase, cloud point determinations were performed with the additions of buffer, dye and inorganic salts. The procedure for the determination of critical temperature was the same as above, bu t using only a fixed surfactant concentration. The phase diagram for Triton X-100 was obtained by measuring the cloud point temperature of aqueous surfactant solutions at different concentrations. 2.1.2.2.2 Spectra and calibrated graph The concentration of the dye was determined by U.V-visible spectrophotometer (PerkinElmer lamda-25). Pure BTB was initially calibrated separately for different concentrations in terms of absorbance units, which were recorded at wavelength 430 nm, at which maximum absorption takes place (Figure 2.1.2, 2.1.3). No significant change in the absorbance has been observed even in the presence of TX-100. Therefore all the absorbance measurements were performed at this wave length. Figure 2.1.2 Spectra of BTB dye Figure 2.1.3 Calibration curve of BTB dye 2.1.2.2.3 Determination of Phase volume Ratio, Fractional coacervate phase volume and pre-concentration factor The volumes of the respective surfactant-rich and aqueous phases obtained after the separation of phases were determined using calibrated centrifuge tubes for calculating the pre concentration factor. Surfactant solutions containing typical amounts of the BTB were extracted using the CPE procedure, followed by the measurement of the respective phase volumes. The results reported are the average of three determinations. The phase volume ratio is defined as the ratio of the volume of the surfactant-rich phase to that of the aqueous phase. It is calculated using the following formula. (2.1.1) Where RV is the phase volume ratio, VS and VW are volumes of surfactant-rich phase and aqueous phase respectively. The pre-concentration factor, (fC) is defined as the ratio of the volume of bulk solution before phase separation (Vt) to that of the surfactant-rich phase after phase separation (Vs). (2.1.2) Where Vt and VS are the volumes of the bulk solution before phase separation and the surfactant-rich phase respectively. The fractional coacervate phase volume with the feed surfactant concentration is calculated by using the relationship: (2.1.3) Where FC is the fractional coacervate volume and Cs is the molar concentration of the feed surfactant solution, for fixed feed dye concentration, the parameters a and b vary linearly with temperature. The value of Fc lies in between 0.04-0.23 for various operating conditions. Surfactant partition coefficient (m) is defined as the ratio of concentration of surfactant in coacervate and dilute phase. - (2.1.4) The efficiency of extraction is defined as - (2.1.5) 2.1.4 Discussion: This section is divided into four parts. In first part, factors influencing the extraction efficiency (e.g., concentrations of non-ionic surfactants, dye and salt, temperature and pH of the solution), fractional coacervate phase volume have been discussed. The nature of solubilization isotherm at different temperature has been presented in the second part. In the third and fourth parts, thermodynamic parameters and a calculation procedure for the determination of surfactant requirement for the dye removal to a desired level is briefly discussed. 2.1.4.1 Factors influencing efficiency: For ionizable solutes, the charge of the solute can greatly influence its extent of binding to a micellar assembly [34]. The ionic form of a molecule normally does not interact with and bind the micellar aggregate as strongly as does its neutral form. Thus adjustment of the solution pH for maximum extractability is of special importance when controlling experimental variables in CPE. With increasing pH, the efficiency of extraction increases up to pH 8.0 and then decreases. This is in accordance with the decrease in cloud point till pH 8.0 and a sudden increase at pH 9.2. Further, the pK value of BTB is 7.1. In the absence of any buffer solution, pH of the dye solution is 7.0 and there is no change in pH event after the extraction process is completed. Hence, all the parameters were optimized at this fixed pH of the medium. No significant increase in efficiency is observed with increasing [Dye] since the cloud point is not altered much with increasing the concentration of dye. The extraction efficiency of dye increases with the increase of surfactant concentration. The concentration of the micelle increases with the surfactant concentration, resulting in more solubilisation of dye in micelles. The surfactant concentration in the dilute phase remains constant (and equal to around CMC); the surfactant concentration along with the solubilised dye in the coacervate phase (micellar phase) increases to maintain the material balance[42-46]. The extraction of dye with TX-100 solution is due to hydrophobic interaction between BTB and hydrophobic micelles in the solution. However, with the increase of TX-100 concentration, the analytical signal becomes weak due to the increase in the final volume of the surfactant rich phase that causes pre concentration factor (phase volume ratio) to decrease [35]. In view of these observations, a 0.04 mol/dm3 triton X- 100 is used throughout. It has been shown that the presence of electrolyte can change the CP in different ways[36]. Salting out electrolyte such as NaCl, decreases the cloud point temperature. They can promote the dehydration of ethoxy groups on the outer surface of the micelles, enhancing the miceller concentration leading to solubilisation of more dye and resulting in a more efficient extraction [37] and reduce the time required for phase separation. A lower salt concentration gives a smaller pre concentration factor, due to the larger volume in the surfactant-rich phase at lower salt concentrations [38]. As shown in the fig the ability of salts to enhance extraction efficiency of the dye was in the order of Na2SO4>NaCl. Temperature has pronounced effect on the extraction of solute. (i) At high temperature, CMC of non-ionic surfactant decreases. (ii) the non-ionic surfactant becomes more hydrophobic due to dehydration of ether oxygen [39] and increase in micellar concentration and solubilization. A general preconcentration factor of 20-60 was obtained with this CPE method and similar pre concentration has been reported for other analytes (40). Typical preconcentration factors reported in the literature[41] varà ¯ed fiom 10 to 100. The CPE method gives a better preconcentration factor compared to conventional solvent extraction methods. In general, high pre concentration factors in CPE can be achieved using small amounts of surfactants which have large capacity to accommodate dye molecules. The hydrated nature and relative polarity of micelles, on the other hand, limit the extraction of dye into the surfactant-rich phase. From the viewpoint of concentrating the analytes present in aqueous solutions, the larger pre concentration factor, e.g., the smaller phase volume in the surfactant-rich phase is desired. A lower surfactant concentration gives a higher pre concentration factor. However, it becomes very difficult for sampling and accurate analysis with a very small volume of the surfactant-rich phase. On the contrary, excessive amount of added salt of ââ¬Å"salting-outâ⬠effect can give the higher pre concentration factor, but it is likely forming the very viscous liquid crystalline phase, instead of the fluidic Liquid phase, in the system, making it difficult to separate the surfactant-rich phase. Therefore, optimization of the pre concentration factor is very critical in a feasible CPE technique. Hence, surfactant concentration of 0.04 mol/dm3 was chosen to conduct CPE experiments in this research. 2.1.4.2 Solubilization isotherm: The adsorption isotherm relating moles of solute solubilized per mole of surfactant[50] are presented in Figure2.1.8. The isotherm can be expressed according to Langmuir type expression: (2.1.6) Where, both m and n are functions of temperature. Figure 2.1.8 Solubilisation curve of BTB dye Assuming a homogeneous monolayer adsorption, the linearized Langmuir sorption model of equation (2.1.6) can be written as: (2.1.7) Plot of 1/qe vs. 1/Ce over the entire dye concentrations was linear with a correlation coefficient of 0.983 as shown in Figure 2.1.9. Thus, the solubilization of dye obeys the Langmuir adsorption model. The calculated values of Langmuir parameters m and n from the slope and intercept of the linear plot of 1/qe vs. 1/Ce were found equal to 4.29X 10-3 (mol/mol) and 2.04X104 dm3 /mol, respectively. Figure 2.1.9 Langmuir isotherm of BTB dye 2.1.4.3 Thermodynamic parameters: The overall thermodynamic parameters ÃâG0, ÃâS0 and ÃâH0 were calculated using equations (2.1.8, 2.1.9) [48,49]as follows. (2.1.8) - (2.1.9) Where T is the temperature in (K), qe/Ce is called the solubilization affinity. ÃâS0 and ÃâH0 are obtained from a linear plot of log (qe/Ce) versus (1/T), from Eq. (2.1.8) and. Once these two parameters are obtained, ÃâG0 is determined from Eq. (2.1.9) and presented in Table 2.1.6. Plot of log (qe/Ce) versus (1/T) is shown in Figure 2.1.10. Table 2.1.6 : Thermodynamic parameters Temp = 80à ±0.1Ãâ¹Ã
¡c; [BTB]initial =12.8010-5 mol/dm3 ; [TX-100] =4.010-2 mol/dm3 pH ( à ±0.05) -à ¢Ãâ â⬠G ( KJ/mole ) à ¢Ãâ â⬠S ( KJ/mole/K ) à ¢Ãâ â⬠H ( KJ/mole ) 353 343 333 6.0 19.57 16.93 14.28 0.27 73.92 7.0 22.11 18.75 15.38 0.34 96.76 8.0 21.10 18.63 16.16 0.25 66.06 Figure 2.1.10 log (qe/Ce) versus (1/T) 2.1.4.4 Design of experiment: The amount of surfactant required can be evaluated from the residual dye present in the dilute phase of the solution after conducting cloud point extraction can be determined [45]. qe is the mole of dye solubilized per mole of non-ionic surfactant. (2.1.10) Moles of dye solubilized can be obtained from mass balance equation, (2.1.11) (2.1.12) Where, A is the moles of dye solubilized in the micelles, V0 and Vd are the volume of the feed solution and that of the dilute phase after CPE, C0 and Ce are concentration of the BTB dye after CPE respectively; Cs is the concentration of surfactant in feed. From the equation 2.1.10, 2.1.11 and 2.1.12 we can write, (2.1.13) Moles of dye solubilized can be obtained from mass balance equation, Where, qe is the mole of dye solubilized per mole of non-ionic surfactant, x is moles TX-100 used, A is the moles of dye solubilized in the micelles, V0 and Vd are the volume of the feed solution and that of the dilute phase after CPE, C0 and respectively; Cs is the concentration of surfactant in feed. (2.1.14) Now, by involving the definition of fractional coavervate volume in the above equation we get, (2.1.15) - (2.1.16) Where a,b are the parameters a and b which are functions of temperature. Substituting the above equation in equation (8) we get, - (2.1.17) Substituting the above equation in equation (1) and rearranging we get, (2.1.18) From the above equation the desired surfactant required (Cs) can be obtained knowing the value of m and n the Langmuir constants, a and b the operating temperature constants, Ce the amount of dye in dilute phase after cloud point extraction. By using the above equation experiments which are conducted were compared for surfactant used and required are shown in Table 2.1.8. Table 2.1.8: Comparison data of required and used TX-100 at 80Ãâ¹Ã
¡C 105 [BTB]initial mol/dm3 105[ BTB]dilute mol/dm3 102[ TX-100 ]used mol/dm3 102[ TX-100 ]Required mol/dm3 3.20 1.11 4.00 2.64 6.40 1.87 4.00 3.82 8.00 2.22 4.00 4.32 9.60 3.19 4.00 3.79 12.80 4.09 4.00 4.46 16.00 6.72 4.00 3.74 8.00 3.60 3.00 2.42 8.00 1.73 4.50 4.32 8.00 1.18 5.00 5.60
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